Product ID:264598, TERMIDOR SC TERMITICIDE / INSECTICIDE
MSDS Date:02/21/2001
FSC:6840
NIIN:01-483-3068
MSDS Number: CLLYZ

Emergency Phone: (800) 424-9300

Info Phone: (800) 331-2867

Preparer: DEPT OF REGULATORY AFFAIR

Cage: UO368

Telephone: 201-871-0771

Cage: 0T7B9

FIPRONIL

CAS: 120068-37-3

INERT INGREDIENTS

Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN: HARMFUL IF ABSORBED THROUGH THE
SKIN. DO NOT GET ON SKIN OR CLOTHING. MAY PRODUCE SYMPTOMS SIMILAR
TO THOSE FROM INGESTION. MAY CAUSE IRRITATION, REDNESS, SWELLING.
EYES: CAUSES EYE IRRITATION. MAY CAUSE REDNESS, TEARING. DO NOT
GET IN EYES. INHALATION: HARMFUL IF INHALED. DO NOT BREATHE SPRAY
MIST. MAY PRODUCE SYMPTOMS SIMILAR TO THOSE FROM INGESTION. MAY
CAUSE SHORTNESS OF BREATH, EXCITE MENT, INVOLUNTARY SHAKING,
IRRITABILITY. INGESTION: HARMFUL IF INGESTED. MAY CAUSE SHORTNESS
OF BREATH, DROWSINES, INVOLUNTARY SHAKING, MUSCLE WEAKNESS,
CONVULSIONS.
Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY
SUBSTANCES THAT ARE CONSIDERED BY OSHA, NTP, IARC, OR ACGIH TO BE
PROBABLE OR SUSPECTED HUMAN CARCINOGENS.
Effects of Overexposure:SKIN: MAY PRODUCE SYMPTOMS SIMILAR TO THOSE
FROM INGESTION. MAY CAUSE IRRITATION, REDNESS, SWELLING. EYES:
CAUSES EYE IRRITATION. MAY CAUSE REDNESS, TEARING. INHALATION: MAY
PRODUCE SYMPTOMS SIMILAR TO THOSE FROM INGESTION. MAY CAUSE
SHORTNESS OF BREATH, EXCITEMENT, INVOLUNTARY SHAKING, IRRITABILITY.
INGESTION: MAY CAUSE SHORTNESS OF BREATH, DROWSINES, INVOLUNTARY
SHAKING, MUSCLE WEAKNESS, CONVUL SIONS.
Medical Cond Aggravated by Exposure:INHALATION OF PRODUCT MAY AGGRAVATE
EXISTING CHRONIC RESPIRATORY PROBLEMS SUCH AS ASTHMA, EMPHYSEMA, OR
BRONCHITIS.

First Aid:SKIN: TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY
WITH PLENTY OF WATER FOR 15-20 MINUTES. EYES:FLUSH EYE WITH PLENTY
OF WATER. CALL A PHYSICIAN IF IRRITATION PERSISTS. INHALATION: MOVE
PER SON TO FRESH AIR. IF PERSON IF NOT BREATHING, CALL 911 OR
AMBULANCE, THEN GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH TO
MOUTH, IF POSSIBLE. INGESTION: HAVE THE PERSON SIP A GLASS OF
WATER IF ABLE TO SWALLOW. DO NOT INDUCE VOMITING UNLESS TOLD TO BY
A POISON CONTROL CENTER OR DOCTOR. ALL ROUTES: CALL A POISON
CONTROL CENTER OR DOCTOR FOR FURTHER TREATMENT ADVICE.

Flash Point Method:CC
Flash Point:>93.C, 199.4F
WILL BURN.
Lower Limits:NO DATA
Upper Limits:NO DATA
Extinguishing Media:FOAM, WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. KEEP
UNNECESSARY PEOPLE AWAY, ISOLATE HAZARD AREA & DENY ENTRY. EVACUATE
RESIDENTS WHO ARE D OWNWIND OF FIRE. DIKE AREA TO PREVENT RUNOFF
AND CONTAMINATION OF WATER SOURCES. DISPOSE OF FIRE CONTROL WATER
LATER.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. HAZARDOUS
DECOMPOSITION MATERIALS (UNDER FIRE CONDITIONS): HYDROGEN FLUORIDE,
OXIDES OF NITROGEN, OXIDES O F SULFUR, OXIDES OF CARBON,
HYDROCHLORIC ACID. (SEE OTHER INFO)

Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE GEAR FOR THE
SITUATION. PUMP ANY FREE LIQUID INTO AN APPROPRIATE CLOSED
CONTAINER. RECOVER AS MUCH LIQUID PRODUCT AS POSSIBLE. ABSORB WITH
AN INERT ABSORBENT. WASH SPILL SI TE WITH A 2-5% CAUSTIC SODA
(SODIUM HYDROXIDE) SOLUTION. IF SPILLED ON THE GROUND, THE AFFECTED
AREAS SHOULD BE SCRAPED CLEAN & PLACED IN AN APPROPRIATE CONTAINER
FOR DISPOSAL. "SEE OTHER INFORMATION"

Handling and Storage Precautions:DO NOT BREATHE VAPORS OR SPRAY MISTS.
DO NOT GET ON SKIN, IN EYE OR ON CLOTHING. DO NOT INGEST. DO NOT
CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL. STORE
UNUSED PRODUCT IN ORIGINAL CONTAIN ER ONLY, OUT OF REACH OF
CHILDREN AND ANIMALS. KEEP OUT OF DIRECT SUNLIGHT.
Other Precautions:STORE IN AN AREA THAT IS COOL, AWAY FROM IGNITION
SOURCES, AWAY FROM FOODSTUFFS, FERTILIZERS, SEED, AND WATER
SOURCES. STORE IN CLOSED CONTAINERS. MINIMUM / MAXIMUM STORAGE
TEMPERATURES NOT AVAILABLE.

Respiratory Protection:ALL PESTICIDE HANDLERS MUST WEAR A DUST/MIST
FILTERING RESPIRATOR (MSHA/NIOSH APPROVAL NUMBER PREFIX TC-21C) OR
A NIOSH APPROVED RESPIRATOR WITH ANY N, R, P, OR HE FILTER WHEN
WORKING IN A NON-VENTILA TED SPACE, INCLUDING BUT NOT LIMITED TO
CRAWL-SPACES AND BASEMENTS.
Ventilation:LOCAL EXHAUST VENTILATION AT THE POINT OF GENERATION.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ALL PESTICIDE HANDLERS MUST WEAR PROTECTIVE EYEWEAR.
Other Protective Equipment:ALL PESTICIDE HANDLERS (MIXERS, LOADERS, AND
APPLICATORS) MUST WEAR LONG-SLEEVED SHIRT AND LONG PANTS, SOCKS,
SHOES, AND CHEMICAL-RESISTANT GLOVES.
Work Hygienic Practices:DO NOT STORE, USE, AND/OR CONSUME FOODS,
BEVERAGES, TOBACCO PRODUCTS, OR COSMETICS IN AREA WHERE THIS
MATERIAL IS STORED. WASH HANDS AND FACE THOROUGHLY WITH SOAP AND
WATER.
Supplemental Safety and Health
THESE RECOMMENDATIONS PROVIDE GENERAL GUIDANCE FOR HANDLING THIS
PRODUCT. BECAUSE SPECIFIC WORK ENVIRONMENTS AND MATERIAL HANDLING
PRACTICES VARY, SAFETY PROCEDURES SHOULD BE DEVELOPED FOR EACH
INTEND ED APPLICATION. WHILE DEVELOPING SAFE HANDLING PROCEDURES,
DO NOT OVERLOOK THE NEED TO CLEAN EQUIPMENT.

HCC:T5
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Vapor Pres:NOT AVAILABLE
Spec Gravity:1.24 @ 25C (77F)
pH:7.22 @1 WT/WT%
Viscosity:300 TO 400 CPS @24C (75F)
Appearance and Odor:A LIGHT BROWN VISCOUS LIQUID; ODORLESS.

Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:DIRECT SUNLIGHT, EXTREME HEAT, OPEN FLAME,
SPARK.
Hazardous Decomposition Products:THERMAL: HYDROGEN FLUORIDE, OXIDES OF
NITROGEN, OXIDES OF SULFUR, OXIDES OF CARBON, HYDROCHLORIC ACID.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:PESTICIDE WASTES ARE ACUTELY HAZARDOUS. IMPROPER
DISPOSAL OF EXCESS PESTICIDE IS A VIOLATION OF FEDERAL LAW. PLEASE
BE ADVISED THAT STATE & LOCAL REQUIREMENTS FOR WASTE DISPOSAL MAY
BE MORE RESTRICTIV E OR OTHERWISE DIFFERENT FROM FEDERAL LAWS &
REGULATIONS. CONSULT STATE & LOCAL REGULTIONS REGARDING THE PROPER
DISPOSAL OF THIS MATERIAL.

Toxicological Information:EYE IRRITATION, RABBIT. MILDLY IRRITATING.
SKIN IRRITATION, RABBIT. SLIGHTLY IRRITATING. SKIN SENSITIZATION,
GUINEA PIG. NOT SENSITIZING. LD50 - LETHAL DOSE 50% OF TEST
SPECIES, >2,000 MG/KG, RA BBIT. LC50- LETHAL CONCENTRATION 50% OF
TEST SPECIES, >1.7 MG/1/4 HR, RAT. LD50 - LETHAL DOSE 50% OF TEST
SPECIES, >1,999 MG/KG, RAT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THIS PESTICIDE IS TOXIC TO BIRDS, FISH, & AQUATIC
INVERTEBRATES. DO NOT APPLY DIRECTLY TO WATER, OR TO AREAS WHERE
SURFACE WATER IS PRESENT OR TO INTERTIDAL AREAS BELOW THE MEAN HIGH
WATER MARK. RUNOF F FROM TREATED AREAS MAY BE HAZARDOUS TO AQUATIC
ORGANISMS IN NEIGHBORING AREAS. CARE MUST BE TAKEN TO AVOID RUNOFF.
DO NOT CONTAMINATE WATER BY CLEANING EQUIPMENT OR DISPOSAL OF
WASTES. DO NOT CONTAM INATE WATER WHEN DISPOSING OF EQUIPMENT
WASHWATERS.

Transport Information:NOT REGULATED FOR TRANSPORTATION.

SARA Title III Information:SARA TITLE III HAZARD CLASSES: FIRE HAZARD,
ACUTE HEALTH HAZARD, & CHRONIC HEALTH HAZARD. SARA 313: NO
COMPONENTS LISTED.
State Regulatory Information:THIS PRODUCT DOES NOT CONTAIN ANY
COMPONENTS THAT ARE REGULATED UNDER CALIFORNIA PROPOSITION 65. THE
FOLLOWING CHEMICALS ASSICIATED WITH THE PRODUCT ARE SUBJECT TO THE
RIGHT-TO-KNOW REGULATIONS IN TH ESE STATES: NO COMPONENTS
REGULATED.